Shard of Naydra's Spike
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When fused to a weapon, turns weapon into ice weapon
"An incredibly hard stone mined from a spike on Naydra's back. It is very destructive when fused to a weapon, and it also imbues that weapon with the power of ice."
Shard of Naydra's Spike is a material found in Tears of the Kingdom.
Tears of the Kingdom
Shards of Naydra's Spikes can be obtained by running along Naydra's back and gathering the small spikes which protrude from the edges of the main spikes - note that doing so without taking damage requires Cold Resistance, such as from the Snowquill Set. When fused to a weapon, they make the weapon blunt, but also turn the weapon into an ice weapon akin to a Frostblade or Frostspear. When fused to a shield, they increase friction while Shield Surfing, but boost a shield bash attack. Carrying such a Fused Weapon or Fused Shield lowers Link's temperature, which can reduce the need for Heat Resistance.
Fifteen shards are needed to upgrade the Tunic of the Wild to ★★★★ level, but there are no quests which require them. They can be sold to shop-vendors all over Hyrule for 30 Rupees each, or used as a light blue dye ingredient at the Kochi Dye Shop.