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King's Scale is a material from Tears of the Kingdom.
Tears of the Kingdom
"Zora kings bear this scale on their foreheads. It sparkles in different ways depending on the angle from which it's viewed. They were once used in ancient Zora ceremonies"
King's Scales can be acquired from King Dorephan in a set of 5. Link can only get more if he has none left in the inventory.
Tears of the Kingdom Hyrule Compendium default picture of a King's Scale