Super Mario RPG and Kirby Super Star can contend with ALttP as best SNES game, IMO. I usually think of the GBA remaster when I think of ALttP anyway, haha.
Well, not necessarily. To the general consumer, buying the base game then buying a remake would sort of seem like money wasted. So I'm just taking the best bet and that is assuming our good buddy Roy here is of the general consumer type. Besides, playing the remake first in my opinion is just like watching the movie before reading the book:
If you experience the later product first then get back to the roots sometime afterwards, you won't be *as* disappointed with the later product.
And I heavily disagree about your point of making ALttP3D being a bad idea. I mean, this is the first time Nintendo has ever embarked (well, assuming they do that is) on such an amazing mission. We sort of already have a functional ALttP3D in the form of Ocarina3D, but it just isn't the same.